1-Aminopyridinium triiodidoplumbate(II)
نویسندگان
چکیده
The title complex, (C(5)H(7)N(2))[PbI(3)], consists of a 1-amino-pyridinium cation, disordered about a mirror plane, and a [PbI(3)](-) anion. The Pb(2+) ion (site symmetry ) is surrounded by six I atoms in a slightly distorted octa-hedral coordination. The PbI(6) octa-hedra share faces, building up (∞) (1)[PbI(6/2)] chains running along [010]. The cations are situated between the chains. Coulombic attractions and van der Waals inter-actions between the inorganic and organic components are mainly responsible for the cohesion of the structure.
منابع مشابه
Bis(4-aminopyridinium) bis(oxalato-κ2 O,O′)cuprate(II) dihydrate
The Cu(II) atom in the title salt, (C(5)H(7)N(2))(2)[Cu(C(2)O(4))(2)]·2H(2)O, is located on a center of inversion and is chelated by two oxalate groups in a square-planar coordination geometry. The cation, anion and water mol-ecules inter-act through hydrogen bonds, forming a three-dimensional hydrogen-bonded network.
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متن کامل3-Aminopyridinium 4-hydroxy-3-iodonaphthalene-1-sulfonate dihydrate
In the hydrated title salt, C(5)H(7)N(2) (+)·C(10)H(6)IO(4)S(-)·2H(2)O, the component species are linked by O-H⋯O and N-H⋯O hydrogen bonds, forming an infinite three-dimensional framework.
متن کامل2-Aminopyridinium (2-aminopyridine)trichloridonickelate(II)
In the title compound, (C(5)H(7)N(2))[NiCl(3)(C(5)H(6)N(2))], the Ni(II) atom is four-coordinated by three chloride anions and one N atom of a 2-amino-pyridine ligand, forming a distorted tetra-hedral coordination. In the crystal structure, cations and complex anions are linked into chains along the a, b and c axes by N-H⋯Cl hydrogen bonds, leading to the formation of a three-dimensional framew...
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عنوان ژورنال:
دوره 66 شماره
صفحات -
تاریخ انتشار 2010